• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:

    公开号:SU1639425A3
    申请号:SU894613322
    申请日:1989-01-27
    公开日:1991-03-30
    发明作者:Фукамахи Хигару；Шумахер Горст；Беверт Вольфганг；Шнейдер Иоахим
    申请人:Басф Аг (Фирма)；
    IPC主号:
    专利说明:

    one
    (21) 4613322/04
    (22) 01.27.89
    (31) 17232
    (32) 01/29/88
    (33) JP
    (46) 03/30/91. Bul № 12
    (71) BASF AG (DE)
    (72) Higaru Fukamahi (JP), Horst Schumacher, Wolfgang Evert, and Joachim Schneider (DK)
    (53) 547.26.118 (088.8)
    (56) Japanese Application No. 59-122424, cl. C 07 C 175/00, published 1984
    (54) STABILIZER FOR THE SENSITIVE OXIDATION OF VITAMINS, TOCOPHEROLS AND CAROTINOIDS
     (57} The invention relates to: a stabilizer for oxidatively sensitive vitamins, tocopherols and carotenoids. In order to increase the stabilizing effect, the stabilizer has the following ratio of components, wt%: hydrocarbon base 68.75-83.30; the additional component is the rest. As a hydrocarbon base contains a substance selected from the group of soybean oil, corn oil, peanut oil, triglyceride of caprylic and capric acids. As an additional component contains a complexing agent, from the group including phytic acid, sodium phytate, calcium phytate, phosphoric acid, sodium hexametaphosphate, sodium tripolyphosphate, cysteine, ethylenediaminetetraacetic acid sodium salt.
    with SS
    The invention relates to compositions having antioxidant properties, and can be used to stabilize substances that are sensitive to oxidation by oxygen in the air during storage.
    The purpose of the invention is to increase the stabilizing effect of the stabilizer.
    The proposed stabilizer is obtained by simply mixing the two components of the composition.
    Example 1, K previously obtained by heating the mixture, wt.h .: water 600; gelatin 220, ethoxyquin 72, sugar 132, dibutyloxytoluene 7.2, vitamin A 220 acetate, vitamin Ve acetate 3.8, with stirring, a stabilizer containing, m.ch,: soybean oil 68.75 and 50 % phytic acid 20. The resulting dispersion of vitamins is fed into the irrigation tower for spraying. It is then dried using a fluid bed dryer. 1 A powder of vitamins A and D is obtained, 1 g of which is placed in a glass bottle, which is stored at a constant temperature of 0 ° C and a relative humidity of 70% for 2 months. After the first month and after the end of the experiment, the remaining vitamin A content is determined in percent of its initial content, i.e. the content of vitamin a in perg
    O5 CO
    CO 4
    you ate

    s
    163 90%, and in the BTO
    BOM case is rum - 86%,,
    Example la (comparative). The obtained preparation of vitamins A and D3 according to example 1 is stored in the specified conditions without the addition of the proposed stabilizer, as a result, after 1 month the content of vitamin A is 59%, and after 2 months - 40%.
    Example 16 (comparative). The obtained vitamins A and D according to the example) stabilize 64 hours of the known stabilizer consisting of; wt.%: Dextrin 25; gum ara bik 25; ascorbic acid 25; tocopherol 25. After 1 month, the content of vitamin A is 72%, and after 2 months - 65%,
    Example 2, K previously obtained by heating the mixture, wt. water 180; glucose syrup 122; gelatin 52.3; Vitamin A acetate 52.4 (2.1 psig / IU / g stabilized with 100 mg ethoxyquin / mil m.e.) J Vitamin D3 0.55 acetate while stirring, add a stabilizer consisting of 2.3. including (16.7 wt.%) phytic acid and 11.5 hours (8343 wt.%) soybean oil. The resulting emulsion is sprayed as in Example 1, and the product obtained is dried in a stream of nitrogen. The obtained vitamin powder in the amount of 3.8 g is mixed with 1 kg of animal feed, consisting of: mas,%: wheat bran 76t, liquid chlorine chloride 75% choline chloride and 25% water 13.3; a mixture of trace elements 10, a mixture of trace elements consists of.% oil: five
    water sulAat copper Zy, D4; ferrous sulphate of iron 46.78; zinc oxide 11.78, manganese oxide 3.61, cobalt carbonate 0.39. The resulting mixture is divided into samples weighing 100 g, which are stored in an air-conditioned cabinet for 8 weeks at 40 ° C and a relative humidity of 70%, after which the remaining content of vitamin D 3 (as a percentage of the initial content) is determined. In all cases, samples remaining content is 81%.
    Example 2a (comparative). When storing food in Example 2 without adding a stabilizer under the specified conditions, the content of vitamin DJ is on average 30%, and when storing food with the addition of a known stabilizer, the prototype that contains
    0
    five
    five
    0
    five
    0
    five
    0
    five
    It contains dextrin, gum arabna, ascorbic acid, and tocoLerol, the vitamin D content is an average of 42%.
    Example 3 Example 2 is repeated, with the difference that a mixture of 170 parts of water, 53 hours, gelatins, 100 hours, glycosic syrup and 52 parts of vitamin A acetate (2.12 million units) is obtained previously by heating. / g; stabilized 100 mg of ethoxyquin / million units and 14.5 mg of dibutyloxytoluene / million units, with stirring, add a stabilizer consisting of 10 hours (71.42 wt.%) of corn oil and 4 4v (28.58 wt.%) 50% phytic acid. After 2 months, the content of vitamin A in all samples is another 54%.
    Example For (comparative). Example 3 is repeated with the difference that the vitamin containing the feed is stored without the addition of a stabilizer. At the same time, after 1 month the content of vitamin A B is, on average, only 17%.
    Example 36 (comparative) Example 3 is repeated, with the difference that 14 hours are used as a stabilizer, a mixture consisting of 25 wt.% Dextrin, 25 wt.% Gum arabic, 25 wt.% Ascorbic acid and 25 wt.% tocopherol. After 7. months, the vitamin A content in all samples is 36%.
    Example 4 Example 3 is repeated, with the difference that 12 hours are used as a stabilizer: 83.3 wt.% Soybean oil and 16.7 wt.% 50% phytic acid. After 2 months, the content of vitamin A in all samples is still 59%.
    Example 5. Example 3 is repeated, with the difference that 12 hours are used as a stabilizer, mixtures: 83.3 wt.% Soybean oil and 16.7 wt.% Phosphoric acid. After 2 months, the content of vitamin A in all samples is 63% /
    Example 6 Example 3 is repeated, with the difference that 12 hours are used as a stabilizer, mixtures: 83.3% by weight of soybean oil and 16.7% by weight,% sodium hexametaphosphate. After 2 months, the vitamin A content in all samples is 53%.
    Example 7. Example 3 is repeated, with the difference that 12 h mixtures are used as a stabilizer: 83.3 May L of soybean oil and 16.7 May 7 sodium tripolyphosphate. After 2 months, the vitamin A content in all samples is 57%,
    Example 8. Example 3 is repeated, with the difference that 12 parts of the mixture are used as stabilizer: 83.3 wt.% Soybean oil and 16.7 wt.% Cysteine. After 2 months, the content of vitamin A in all samples was em 59%.
    Example 9, Example 3 is repeated, with the difference that 12 parts of a mixture of 83.3% by weight,% of synthetic triglyceride based on caprylic and capric acids, commercial product Miglycol 812 and 16.7% by weight of phytate are used as stabilizer. on three . After 2 months, the content of vitamin A in all samples is 54%.
    Example 10. Example 3 is repeated, with the difference that 1 part of the mixture is used as a stabilizer: 71.42% by weight of peanut oil and 28.58% by weight of 5P% phytic acid. After a month, the vitamin A content of all samples is 53%.
    Example 11. Example 3 is repeated, with the difference that 12 hours are used as a stabilizer. mixtures: 83.3 May. soybean oil and 16.7 wt.% sodium ethylenediaminetetraacetic acid. After 2 months, the content of vitamin A in all samples is 59%.
    Example 12. Example 2 is repeated with the difference that to the mixture previously obtained by heating: 150 parts of water; 52.3 parts gelatin 126.8 parts glycosic syrup; 50 parts of tocopherol, with stirring, add stabilizer consisting of 10 hours. (83.3% by weight) of soybean oil and 2 hours (16.7% by weight) of sodium hexametaphosphate. After 1 month, the content of tocopherol in all samples is 49%
    Example 12a (comparative). Example 12 is repeated, with the difference that the feed containing tocopherol is stored without stabilizing agent. After one month, the content of tocopherol averages 18%,
    Example 126 (comparative) Example 12 is repeated, with the difference that 12 parts of a mixture consisting of 40 wt.% Dextrin, 30 wt.% Gum arabic and 30 wt.% Ascorbic acid are used as a stabilizer. After 1 month, the content of tocopherol in all samples is
    32%.,
    Example 13. Example 2 is repeated, with the difference that to a mixture of 68.7 parts of water previously prepared by heating, 19.2 hours.
    5 gelatins, 1.5 parts of ethoxyquin, 9.7 parts of sucrose; 0.3 hour, ascorbyl palmitate and 4.5 parts of citranaxanthine were added with stirring, a stabilizer consisting of K, 7 hours (80.95% by weight) of white oil and 0.4 hours, (19.05% by weight %) calcium salt of phytic acid. After 1 month, the content of citranaxanthin in all samples is 68%.
    5 Example 1 Over (comparative). Example 13 is repeated, with the difference that the citranxanthine-containing feed is stored without the addition of a stabilizer. After 1 month, the content of cy0 ranaxanthin in samples is on average 7.0%.
    Example 136 (comparative). Example 13 is repeated, with the difference that 2.1 h is used as a stabilizer, a mixture consisting of 25 wt.% Dextrin, 25 wt.% Gum arabic, 25 wt.% Ascorbic acid, and 25 wt.% Tocopherol. After 1 month, the content of zintranaxanthio in the samples is 40%.
    Example 14. Example 2 is repeated, with the difference that the mixture of 106.8 parts of water, 29 parts of yellow, 3.8 parts of ethoxyquin, 47.3 parts of sucrose and 13 is obtained by heating the mixture. , 3 h, micronized canthaxanthin with stirring add stabilizer consisting of 4h. (83.3 wt.%) Soybean oil and
    0 0.8 hours (16.7% yas.) Of phytic acid. After 1 month, the content of cantaxanthin in the samples is 79%.
    Example 14a (comparative).
    5 Example 14 is repeated, with the difference that canthaxanthin-coder feed is stored without the addition of a stabilizer. After 1 month, the content of cantaxanthin is on average 33%.
    Example 146 (comparative). Example 14 is repeated, with the difference that 4.8 parts of a mixture consisting of 25 wt.% Dextrin, 25 wt.% Gum arabic, 25 wt.% Ascorbic acid and 25 wt.% Tocopherol are used as a stabilizer. After 1 month, the content of canthaxanthin in the samples is 52%.
    权利要求:
    Claims (1)
    [1]
    Invention Formula
    A stabilizer for oxidation-sensitive vitamins, tocopherols, and carotenoids, including the carbohydrate base and. An additional component, characterized in that, in order to increase the stabilizing effect, as a hydrocarbon
    It contains a substance selected from the group: soybean oil, corn oil, peanut oil, triglyceride of caprylic and capric acids, and as an additional component, a complexing agent selected from the group including phytic acid, sodium phytate, calcium phytate, phosphoric acid, sodium hexametaphosphate, sodium tri-polyphosphate, cystine, ethylene diamine tetraacetic acid sodium salt, in the following ratio, wt.%:

    68.75-83.30 Else
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    同族专利:
    公开号 | 公开日
    DK35589D0|1989-01-27|
    DK174663B1|2003-08-18|
    CA1331136C|1994-08-02|
    IL88961A|1992-07-15|
    IN171845B|1993-01-23|
    EP0326026A2|1989-08-02|
    CN1023229C|1993-12-22|
    EP0326026B1|1992-06-17|
    CN1036220A|1989-10-11|
    DE58901641D1|1992-07-23|
    EP0326026A3|1990-11-14|
    IL88961D0|1989-08-15|
    DK35589A|1989-07-30|
    KR890011974A|1989-08-23|
    US4929774A|1990-05-29|
    引用文献:
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    JPH02124894A|1988-11-01|1990-05-14|Sanwa Kagaku Kenkyusho Co Ltd|Stabilized phytic acid composition|
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    法律状态:
    2007-12-20| REG| Reference to a code of a succession state|Ref country code: RU Ref legal event code: MM4A Effective date: 20060128 |
    优先权:
    申请号 | 申请日 | 专利标题
    JP1723288|1988-01-29|
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